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(ϑid\Sm^m 1kgnBR-N@b+Tn(vir(vϑ SIUSMOmol" kg-1 mB = nB/wA nB  n(Bvir(vϑ USMO:Nmol0 wA nBRv(ϑ USMO:Nkg0 c  lK & f " """""*"*""*""*""**" ""*" "     H  0޽h ? ̙3333___PPT10+JDO' = @B D ' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(+8+0+ +  : 2 p (  r  S (r`0  r   c rd 1?"  > 2   c rd 1?"`F > 2   c rd 1?"0U,$D0 2. id\Rpe(bir(vϑRpe)  Nnm-Nv;`ir(vϑdNUONir(vϑ sS:Nir(vid\Rpe /fUSMO:NNvϑ0 gS~Rnm nBRATn(Bvir(vϑR+R:NnATnB RZX 2P  (  ( &   c $A4 ??r 8 $D0  c rd 1?" `f,$D0 0lae gr^yir( id\RpeKNT;`/fI{N10 $f   c $A6 ??S )[ 8 $D0   c $A/ ??  8 $D0H  0޽h ? ̙3333  ___PPT10 +vDL ' = @B D ' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* %(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* %(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(+p+0+ ++0+ +i  $l(  $x $ c $(r   r  $ Tr ??Q b(WN[)n^ N mSOSvQl0Rvs^ae l@bwQ gvSRy:N)n^ NmSOvqTlS {ylS0p2 2%&f&f&f&f&f#1| $ c d 1?",$D 0 `lSN)n^ gNHNsQ|2 2$f    $ c Td 1?"` L,$D0 T{ N TnBRlS N T v TnBR)n^GSؚ lSX'Y0OY p(H2O, l , 298K)=3167 Pa p(H2O, l, 373K)=101.325kPa8 2(2#  4H $ 0޽h ? f33335 - ___PPT10 +U2D' = @B D<' = @BA?%,( < +O%,( < +D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*$D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*$D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$%(D' =-o6Bdissolve*<3<*$+p+0+$ ++0+$ +  xp ((  (x ( c $D`0    ( T! ??p lVirtf[[bLN\nc[_QN N[ϑsQ|(WN[)n^ N %cSv^5u(znmvlS NMpNn(vid\Rpebckk Nn(v,g'`esQ0sS p = pAxB vQ-NxB/fn(B(Wnm-Nvid\Rpe pA/f~nBRv}lS0傶nmv(ϑid\Sm^:NmB R0H 2 (2. 2-       (  (  (  (  ( - : ( c 5d 1?"  ,$D0 D(2  ( c 8d 1?"P,$D0 ( _-N k:NSNnBR'`( gsQv8^pe0: 2!!!, `  ( c $A( Q??, d  Q`  ( c $A1 a??  aH ( 0޽h ? f3333___PPT10+J D ' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(Dj' =K@BB BBPB0B%(/%(D' =1:Bvisible*o3>+B#style.visibility<*(%(D' =-o6Bdissolve*<3<*(D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*(%(D' =-o6Bdissolve*<3<*(+p+0+( ++0+( +   0t(  0x 0 c $H`0    0 TPJ ??p? <NKm[n(RP[vv[id\(ϑ (ϑ:NWBvn(nN(ϑ:NWAvnBR-N R g ( 'f$$,$$,$6  0 S A; X??j/8 X$D0d 0 TT ??@ ,$D0 r^qBR]\OSt CaCl20NaOH0P2O5I{fno㉄vV`ir( 8^(u\Or^qBR0VvQf8T6ezzl-Nv4lR(WvQhbb_bnm 勶nmlSzzl-N4llvRS\ Ozzl-Nv4ll NeQ~ۏeQnm 0Rmdzzl-N4llvvv0 vo &f ( ( (V 6WH 0 0޽h ? f3333e]___PPT10=+期D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*0%(D' =-o6Bdissolve*<3<*0D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*0%(D' =-o6Bdissolve*<3<*0+8+0+0.  +:  #<`\(  <x < c $h`0    < T j ??p flpmSOlS0R101.325kPa(1atm)ev)n^0 l~)n^mSOlSNYLuSRvI{ev)n^0 VSOhbvRP[_NS wQ gN[vlS0VSONvQl(W[핹[hV-NS0Rs^a0Z_(!! !!;!,  D: < Tw ?? ,$D0 %cSir(vnmvlp;`/fؚN~nBRvlp NKN]:N %Tbp = Tbp  Tb = kbp" m kbpy:NnBRvid\lp NGS8^pe USMO:NKkgmol-10 LX $ $$,$$$,$,$ ("    ( (d l      <  ,$D0B <  `D8c?"P P B <  `D8c?"P   < c d 1?" 0  3p 2  < c d 1?"   5T 2Bl p0   <` p@ ,$D0  < S T0e0e    BC`DEF d@  8c 8c8c     ?1 d0u0@Ty2 NP'p<'pA)BCD|E||`T0pp@  S"p0P   < c d 1?"P0 JnBR 2" .l p0  <   ,$D0 <  60e0e    BC`DEF d@  8c 8c8c     ?1 d0u0@Ty2 NP'p<'pA)BCD|E||`T0pp@  S"pP  < s d 1?"P0 Nnm 2& "l P  < P ,$D0B < ZD8c?"P  < c ,d 1?" 0 < 101.325kPa 2 B <  `D8c?" ,$D 0d < s d 1?" @ ,$D 0 hTbp &`2- B <  `D8c?"`` ,$D 0B < s td 1?" 0P ,$D0 FTb $ 2 0l ` P  <` P ,$D 0 < c d 1?"` P  J p<101.325kPa" 2 B < ZD8c?"`  ` < c d 1?"@ ,$D 0 jV3.1 lp NGS:yaV (2 #H < 0޽h ? 3333___PPT10x+:SKD|' = @B D7' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* <%(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* <%(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D' =%(D' =%(D3' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D' =-o6Bwipe(up)*<3<*<D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D' =%(D' =%(D3' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D' =-o6Bwipe(up)*<3<*<DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D%' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<%(++0+<.  ++0+<.  ++0+<.  ++0+<.  +K3  RJD (  Dx D c $̩`0   2 D Tҩ ??P J ,$D0 znmvQVp;`/fNON~nBRvQVp [NKN]:N %Tfp = Tfp Tf = kfp m kfp y:NnBRvid\QVp NM8^pe0NF $ $,$$$,$$,$  ((   (( $ ~V D TX ??P p ,$D0 Byrp Kfp, kbpSNnBRy{| gsQ TynBRkfp kbp  " ,$ (  ,,  (Tt D s 4d 1?"p< HQVpqp mvTVvlSvI{ev)n^  VvNmvqQX[ev)n^0$% 2 "  z     D  0 ,$D0B D  `D8c?"P P B D  `D8c?"P    D c xd 1?" 0  3p 2  D c d 1?"   5T 2 l  @  D@  ,$D0  D c Z0e0e    BC`DEF d@  8c 8c8c     ?1 d0u0@Ty2 NP'p<'pA)BCD|E||`T0pp@  S"    D s d 1?"@ LnBR 2#  D  60e0e    BC`DEF d@  8c 8c8c     ?1 d0u0@Ty2 NP'p<'pA)BCD|E||`T0pp@  S" `   D s d 1?"0 Pnm 2' l  p  D p ,$D0B DB ZD8c?" 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L  fTfp $ 2 n D  d 1?"  ,$D0 fV3.2 QVp NM:yaV" H D 0޽h ? 3333___PPT10y+%D' = @B Dp' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D%' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D%(++0+D.  ++0+D.  ++0+D.  +   H(  Hx H c $L/`0    H T8 ??^,$0 @ Km[RP[vv[RP[(ϑ NQVp NM^(uY0V:Nkfpkbp Tfp Tbp @bN[]\ NQVe g~vfgQ fN‰[0 S_n(vv[id\(ϑMB_'Ye 1uNTf*Y\ Qnx'`] VdkS(uNMB'Yv`Q0 (29(2- 2 &f&f  ,  (   (   (#  (   (  ( # H c `Kd 1?" ,$0 r 2QBR]\OSt Q)Y:N2bk}lf4l{~Q SReQul0YNNI{NMNO4lvQVp MQV~Q SOy O4l{4xˆ0P 1 &f&f1 8H H 0޽h ? 3333___PPT10+R0gD' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*H%(D' =-o6Bdissolve*<3<*HD' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*H%(D' =-o6Bdissolve*<3<*H+p+0+Hq  ++0+Hq  +  L6(  Lx L c $[`0   V L TP] ??@`,$D0 , QQBR]\OSt ]NQQBRY(WQ4l-NR/lSVSO,1uNnm-N4lvlS\NQvlS,OQŏqS 'Yϑ8Tp,OhTVir(v)n^MNO0 ߘv-Q 30g NaCl + 100g H2O(s) -22! CaCl2-Q42.5g CaCl2 + 100g H2O(s) -55! d *(&f&fR ( ( ( (  !  L Tn ??pI,$D0 hT NOqTёv6RY )R(uV`nmQVp NMSt S6RYY g_'Yv[(uN+B#style.visibility<*L%(D' =-o6Bdissolve*<3<*LD' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*L%(D' =-o6Bdissolve*<3<*L+p+0+Lq  ++0+Lq  +?  &-Tb(  Tx T c $`0   @ T T ??P  Vnsa  nBRǏJSۏeQnmbnBRNznmǏJSۏeQSmnmvsaUSTibce &,(2 ( &B T ZD?"P l @    T@  ,$D0 T Z1?"@    T  `1?" l  p   T p ,$D0 T Z1?" p   T  `1?"pB  T ZD8c?" ,$D0 T c .A saltP  ,$D 0l @    T@  ,$D0 T  `1?"@   T  `1?"  T Z1?" p,$D 0~ T C "A Down`p,$D 08 @ p  T@ p B T ZD1?"@ @ B T ZD1?"@ p B T ZD1?"pp B TB ZD1?"pB T ZD1?"B T ZD1?"@  B T ZD1?"  B T ZD1?"pB T ZD1?"B T ZD1?"pppl  pP &T ,$D 0T $T C $A8 Down2 pPB %T ZD1?" p P&l   )T ,$D 0  'T c Ԑd 1?"@ @" 2 B (T ZD8c?" `p *T c Hd 1?" b ,$D 0 <nS  ;bknۏL@beRvg\YS,(uh:y0(Wpe

 +T S AH  ?? YH8  $D 0 ,T Z1?",$D  0` -T c d 1?" p,$D 0 jV3.3 nmnS:yaV(2" H T 0޽h ? 3333f%^%___PPT10>%+3D$' = @B Dm$' = @BA?%,( < +O%,( < +D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<* T%(D' =-o6Bdissolve*<3<* TD' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<* T%(D' =-o6Bdissolve*<3<* TD4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* T%(D+ ' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*T%(D' =+4 8?\CB#ppt_xBCB#ppt_xB*Y3>B ppt_x<*TD' =+4 8?dCB0-#ppt_h/2BCB#ppt_yB*Y3>B ppt_y<*TD' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<* T%(D' =-o6Bdissolve*<3<* TD' =%(D7' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*T%(D' =-s6Bwipe(down)*<3<*TD' =%(D3' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*T%(D' =-o6Bwipe(up)*<3<*TD' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*&T%(D' =+4 8?\CB#ppt_xBCB#ppt_xB*Y3>B ppt_x<*&TD' =+4 8?dCB0-#ppt_h/2BCB#ppt_yB*Y3>B ppt_y<*&TD' =%(D7' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*,T%(D' =-s6Bwipe(down)*<3<*,TD' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*)T%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<**T%(D%' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*+T%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*-T%(+p+0+*Tq  ++0+-Tq  +   zr\ (  \x \ c $$`0    \ T| ??,$0 ZKm[RP[vv[RP[(ϑ nS g'Ype

+B#style.visibility<*\%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*\%(+p+0+\q  ++0+\q  +|   `h(  `x ` c $ƭ`0    ` T0ȭ ??pR,$D0 I{nnm NSO@mvnS~:N780kPa uNl\bme O(u0.9%vNaClnm0.16 moldm-3 b5%va|nm(0.28moldm-3) ُ$NynmN~~ހT@Fm/fI{nnmsSnSvI{ 0f 2j(2&f3 ( (     ` Tԭ ??p ,$D0 NSn YR(Wnm NvSR'YNnS ROOnm-NvnBRT~nBReTAmR O~nBRSOyXR Ǐ zSSn0^l(uNwm4lmS0]N^4lvYtSnmvSm)I{ sQ.(WNؚSJSv6RY0 \_ 2&f&f/  '  ^H ` 0޽h ? 3333LD___PPT10$+LwD' = @B DS' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*`%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*`%(+p+0+`q  ++0+`q  +  d\ d(  dx d c $`0    d TT ??p` %cS^5u(znmv'`((lS NM lp NGSTQVp NM NSnmnS)NN[ϑnBR-Nn(RP[vpevbckk, Nn(,g'`esQvsa,y:NznmvOpe'` _Nyznm[_0 lY 2G&f&f&f&f&f Z   d T ?? ` ,$D 0 T{Smnm-Nn(v_|peY n(_|vvN\O(uSn(_|NnBRRP[vvN\O(u YBg Oznm[_v[ϑsQ|NuOP]0 (W5u(nm-N 1uN5u(v㉻y O_znm[_v[ϑsQ| N(u0&_(2^  ^ d c d 1?"  ,$D 0 8`v TSm^v5u(nmvlSN^5u(kYUOSS2 2$f   d c d 1?" 0,$D 0 XT{vQlS NM lp NGSTQVp NM NSnmnSvpe+B#style.visibility<*d%(D' =-6B#strips(downLeft)*<3<*dD' =%(D' =%(DP' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*d%(D' =-6B#strips(downLeft)*<3<*dD' =%(D' =%(DP' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*d%(D' =-6B#strips(downLeft)*<3<*d++0+dw  ++0+dw  ++0+dw  +}  `X0h(  hx h c $8`0    h T ??,$D 0 D?N<\LNe9hnc5u(nm N gNznm[_vsa cQN5uyt01903t^N_N\Sf[VY05uyt:N5u(RP[(W4lnm-N㉻ybyP[ O_nm-Nv_|peX'Y Ee[Nv}lS0lp0qpv9eSTnSpe+B#style.visibility<*h%(D' =-6B#strips(downLeft)*<3<*hD' =%(D' =%(DP' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*h%(D' =-6B#strips(downLeft)*<3<*hD' =%(D' =%(DC' =4@BBB B%(D' =1:Bvisible*o3>+B#style.visibility<*h%(D' =-6B#strips(downLeft)*<3<*h+p+0+hw  ++0+hw  +  @l(  lx l c $&`0   L l T ??p\,$D0 DO3.1 \(ϑid\Sm^GW:N0.10 molkg-1vBaCl2, HCl, HAc, |4lnmv|P[pe0lS0lp0QVpTnS cN'Y0R\!k^c^:^Q 2$f ( (/ r ! l c Bd 1?" ,$D0 d cN'Y0R\!k^c^Y N |P[pe BaCl2 !HCl ! HAc ! | lS | ! HAc ! HCl ! BaCl2 lp BaCl2 ! HCl ! HAc ! | QVp |! HAc ! HCl ! BaCl2 nS BaCl2 ! HCl ! HAc ! | 2($f      ( 1  (   ( /  (   (   (      H l 0޽h ? 3333LD___PPT10$+?NhD' = @B DS' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*l%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*l%(+p+0+lw  ++0+lw  +    Pv (  r  S L f`0  f   c Pd 1?"`l fNR5u(v0.1molkg-1nmvQVp NMpe  c Yd 1?" ,$0 (B5u( [KmT f / K { Tf / K i= T f /  Tf NaCl 0.348 0.186 1.87 HCl 0.355 0.186 1.91 K2SO4 0.458 0.186 2.46 CH3COOH 0.188 0.186 1.01 h2 p   (    (    (     (  6  (   (   (  Z   PF  c qd 1?"  ,$0 P`SN wQ NuvOP] gN Nĉ_ A2B(AB2):_5u(>AB:_5u(>AB1_5u(>^5u(j1  $f,f$f,f$fb|  c zd 1?"` @F ,$D0 *``O؏>NOf5uytvvQN^(uT& 2$f H  0޽h ? ̙3333LD___PPT10$+~zD' = @B DS' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(+p+0+w  ++0+w  +  xp`p(  px p c $쇱`0   \ p TЉ ??@ ,$D0 H4lnm-NvUSvyP[s^aN,R:Nx0xv㉻ys^aSMyP[v㉻ys^a$N{|0 &% 2#" $ p c d}d 1?"pA,$D0 9hnc㉻y^v'Y\ \5u(R:N:_5u(T1_5u($N{|0:_5u((W4l-NhQ㉻y 1_5u((W4lnm-NS gR㉻y 'YRNNRP[b__X[(W01_5u((W4lnm-NX[(W㉻ys^a0U 2U"TH p 0޽h ? 3333___PPT10+YDO' = @B D ' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*p%(+8+0+pw  +  ptf(  tx t c $h`0    t T ??p` |1. xxvi_ cHQT!k^ xxt;N gN NQy xx5uyt?l4lyP[ (W4lnm-N㉻ye@bubvckyP[hQ/fH+vSTir/fx@bubvyP[hQ/fOHvSTir/fx0xx-NTS^v[(/fH+ + OH = H2O0& (v I( &f &f&f (        (   ( H; t c Pd 1?"0 Q ,$D 0 >xx5uytv:w bx0xv[IN@\PNN4l:NnBRv|~0>   &f   t s d 1?"  ,$D 0 6elʑNH30Na2CO3GW N+TOH _NwQ gx'`0z  ( ( (   . H t 0޽h ? 3333___PPT10+1(=D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*t%(D' =-6B%strips(downRight)*<3<*tD' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*t%(D' =-6B%strips(downRight)*<3<*t+p+0+tw  ++0+tw  +$  .&x(  xx x c $ű`0    x T@DZ ??@P,$D0 4Q~Q(P[vir(/fxQ~T(P[vir(/fx0(""""""""" l   x ,$D0 x c `бd 1?" ,$D0 x0xSN/fRP[ _NSN/fyP[0x~Q(P[TSNQ~T(P[ Vdkx~Q(P[T1\S:Nx x (P[ + x ((P[~NSO ((P[cSSO P,(I , " ,"H@ x x 3 A? ,$D 0 l PP0   xPP0 ,$D0> x c ڱd 1?"PP0 ,$D0 @<Y(W4lnm-N HCl(aq H+(aq) +Cl-(aq) HAc(aq) H+(aq) +Ac(aq) NH4+(aq) H+(aq) +NH3(aq) HCO3-(aq) H+(aq) + CO32-(aq) Al(H2O)63+ H+(aq)+ Al(H2O)5(OH-)2+ x (P[ + x(# ( (" (   (( ( ( (( (  (( ( (( (  ( ( ( (1 !*5*x x 3 A?W@{,$D 0x x 3 A?`I ,$D 0x  x 3 A?pk,$D 0x  x 3 A?`[,$D 0x  x 3 A?  ,$D 0x  x 3 A? y ,$D 0H x 0޽h ? 3333  ___PPT10v +sKD" ' = @B D ' = @BA?%,( < +O%,( < +D ' =%(D' =%(DZ' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*x%(D' =-6B-randombar(horizontal)*<3<*xD' =%(D' =%(DM' =4@BBB B%(D' =1:Bvisible*o3>+B#style.visibility<* x%(D' =-6B-randombar(horizontal)*<3<* xD' =%(D' =%(DM' =4@BBB B%(D' =1:Bvisible*o3>+B#style.visibility<*x%(D' =-6B-randombar(horizontal)*<3<*x+8+0+xz  +  |T(  |x | c $ `0    | T  ??p,$D0 VxN[^vxvُyvNOX[0vNlSvsQ|y:NxxqQmsQ|0x1YS(P[Tb_bvxy:NxvqQmxx~T(P[Tb_bvxy:N勱xvqQmx0qQmxN[vqQmxNwy:NqQmxx[0OY:h] 2."""" """[l  |,$D 0 | s d 1?"  qQmxx[ HAc + H2O H3O+ +Ac- (5uy) HAc/Ac-, H3O+/ H2O H3O+ +NH3 H2O+ NH4 (-NT) NH4 /NH3, H3O+/ H2O H2O+ CN- OH- + HCN (4l) HCN/CN-, H2O/OH- H2O+ CO3 HCO3 + OH(4l) HCO 3/CO3, H2O/OH- "s 2 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( (( ( ( ( ( (>I .41~ | C A?pI YB ,$D 0~ | C A?pY ,$D 0~  | C A?  ,$D 0~  | C A?p Y ,$D 0 | c TOd 1?" O  82- 2* | c Rd 1?" 2  H * 2** | c Vd 1?"    7+ 2* | c +B#style.visibility<*|%(D' =-o6Bdissolve*<3<*|D' =%(D' =%(D3' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*|%(D' =-o6Bwipe(up)*<3<*|+8+0+|z  +  x(  r  S n`0     c Xpd 1?" ,$0 xx(P[tib'YNxxvV [k5uytf^l vQxxv[INSNH+:N$Rnc NnBResQ SNʑNH30Na2CO3NSNH4ClI{vxx'`0I 2""*"*"*"*"* "H! R  s |d 1?"@OZ,$0 Vb$N'`ir(: H2O, HCO3 (@b gx_9h) evvi_: NH4Cl (xx YTir)p2"*"*""* "`p  s 䆳d 1?"O,$0 txx(P[t/fi_vN:Wie&fH  0޽h ? ̙3333  ___PPT10 + D ' = @B D ' = @BA?%,( < +O%,( < +D' =%(D' =%(DP' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B#blinds(vertical)*<3<*D' =%(D' =%(DP' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B#blinds(vertical)*<3<*D' =%(D' =%(DP' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B#blinds(vertical)*<3<*++0+z  ++0+z  ++0+z  +      X (  x  c $`0   r  T ??@\TL___PPT9.&@ QcS5uP[[vir(/fx Q~Q5uP[[vir(/fx,_Ny:Nfexxt0 H + OH = H2O x + x = xxRTirl6(v(,""*"n  FF  k    E    c Dd 1?"P $D 0TL___PPT9.&@  (1) H3BO3 H+ + H2BO3 () H3BO3 + H2O [B(OH)4] + H+ |xx/ffex P,p2d27p222" ( ( ( ( ( (  ( ( ( ( (  "H  '  @`x   3 A? ,$D 0x   3 A?pk ,$D 08        s d 1?"  TLD___PPT9&  Cu2+ + 4NH3 [Cu(NH3)4]2+ m݄r x x RTir xx5uP[tFd1Nx_{+T gHvP6R SbvVf^0(p222%p222p222 ( ( ( ( (,  $$7  @`x  3 A?0  ,$D 0H  0޽h ? 3333y___PPT10Y+D=' = @B +H  h `  (  r  S ׳@0     T`̳ ??0 6~d\pe:_x0:_xY 'YYpexTxnmX[(W㉻ys^a vQs^a8^pey:N㉻y8^peKabKb vQ l  --   -- ,$D0  c &A ?? -- 8 $D0~N     p@p2  N >?"  B   ND>?"P P ~N       ` 2   N >?"  B   ND>?"P P ~N       @ p2  N >?"  B  ND>?"P P H  0޽h ? 3333___PPT10`+2\D' = @B D' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(+p+0+z  ++0+z  +&  LD':P(  x  c $ `0     T  ??` ,$0 NCQ1_xHAvSm^:Nc, ㉻y^:N HA = H+ + A- wYSm^ c 0 0 s^aSm^ c(1-) ca ca( (     ( (          Z l '  #' ,$D0d  S A: ??'  ~N     P02  N >?"  B  ND>?"P P ~N       2  N >?"  B  ND>?"P P ~N      @P p2  N >?"  B  ND>?"P P ~N      @p2 ! N >?"  B " ND>?"P P l P   3P  ,$D0T@ P   -P  j  c &A?  ??P 0   j  c &A  "??uQ   "   s <"d 1?"   PVdk 2 ~N    $   2 % N >?"  B & ND>?"P P ~N    ' @ p 2 ( N >?"  B ) ND>?"P P ~l  01  9 N? ,$D0   Z' ??    r Tt [NNCQ1_x &  2 $  j   c &A $??Q 01  $T    .# ! Q 2 / N >?"  B 0 ND>?"P P l  \ : \,$D0 2 Z(- ?? \ 6znmvx^(H+yP[Sm^)8^(upHh:y pH =  lgc(H+/c ), nmvx^(OHyP[Sm^)S(upOHh:y0> 2$,$$$$,$$$$  $  T    5#   2 6 N >?"  B 7 ND>?"P P H  0޽h ? 3333; 3 ___PPT10 +IJD ' = @B Dz ' = @BA?%,( < +O%,( < +D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*#%(D' =-o6Bdissolve*<3<*#D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*3%(D' =-o6Bdissolve*<3<*3D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*9%(D' =-o6Bdissolve*<3<*9+8+0+|  +  "    (  x  c $M`0   L  THO ??` |DO3.1 ]wHAcvKa =1.7610-5 {3.0%s|(+THAcSm^:N0.50 moldm-3)vpH0 ? $f   (  ( (      T] ??0 ,$ 0 hs|nm-NH+vs^aSm^:Nx moldm-3, R HAc(aq) = H+(aq) + Ac-(aq) s^aSm^/moldm-3 0.50  x x x Ka = 1.7610-5 5"Ka / c10-4 4" 0.50  x H" 0.5 i( !  $f (   ( ( ( (     (   (  ((   (     |  H  S A ?? < } 8 $D 0  S A  ??p n 8 $D 0   S A  ?? K 8 $D 0l t ,  t,,$D 0   Zp| ??t , (jpH =  lg c( H+)/c =  lg(2.9710-3) = 3  0.47 = 2.536 2    .T     # @p2   N >?"  B  ND>?"P P H  0޽h ? 3333 { ___PPT10[ +JGD ' = @B D ' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*D' =%(D' =%(DE' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*D' =%(D' =%(DE' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*D' =%(D' =%(DE' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-6B%strips(downRight)*<3<* +8+0+|  +     ( (  x  c $`0     Tܗ ??` @RO3.2 {0.100 moldm-3 NH4Clnm-NH+Sm^SvQpH0 * 2$f ( ( (  FP  T ??0,$0  NH4Cl(aq) = NH4+(aq) + Cl(aq) NH4+(aq) + H2O(l) = NH3(aq) + H3O+ (aq) Ka =5.6510-10Vl(2f     H0rl <w  <w ,$D0j  c &A9 T??<w  TT    # ~  2   N >?"  B   ND>?"P P l  0   0 ,$D0  Tt ?? 0  DZpH =  lg c( H+)/c =  lg(7.5210-6) = 5.12 . 2    %~N        2   N >?"  B   ND>?"P P H  0޽h ? 3333___PPT10+q8D' = @B DF' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(+8+0+|  +a  ~v'P(  x  c $$ҵ`0   t  Tӵ ??J 0P,$ 0 JYCQ1_x(x)v㉻y/fR~ۏLv kN~㉻y gN*N㉻y8^pe,Nxx:NO& 2& 6Bl Z %Z,$D 0j  c &A *??X *T Z # Zj  c &A ??@Z   Zڵ ?? f N~㉻y $ 2  ~N       2  N >?"  B  ND>?"P P 6l P3@  &P3@ ,$D 0j   c &A ,??2 Z@  ,T P3 # P3d  S A ??3   T$ ??P f N~㉻y $ 2  ~N      2   N >?"  B ! ND>?"P P 6l Pj  'j P,$D 0j  c &A .?? y  .T P@ f  # Pj  d   S A ??@ f    T ??P@ @`  f N~㉻y $ 2  ~N    " `  @2 # N >?"  B $ ND>?"P P H  0޽h ? 3333  ___PPT10c +k:D ' = @B D ' = @BA?%,( < +O%,( < +D' =%(D' =%(DT' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B'barn(inHorizontal)*<3<*D' =%(D' =%(DG' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%%(D' =-6B'barn(inHorizontal)*<3<*%D' =%(D' =%(DG' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*&%(D' =-6B'barn(inHorizontal)*<3<*&D' =%(D' =%(DG' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*'%(D' =-6B'barn(inHorizontal)*<3<*'+8+0+  +   (  x  c $X`0   *  T ?? z_-N Ka,3 << K a,2 << K a,1 k~㉻y8^pe]3^6*Npeϑ~0 Vdk H+Sm^v{NN~㉻y:N;N0>(2  (  (((  (( ( H  j  c ,d 1?",$D 0 tT {H+Sm^e S_Ka,2 / K a,1<103e S_euN0 N~㉻ys^a0 +(2 (  ((  ((  ( >  c d 1?"` ,$D 0 @ kYCQ1_xvx'`:_1_e Sk[NN~㉻y8^pe+B#style.visibility<* %(D' =-6B%strips(downRight)*<3<* D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-6B%strips(downRight)*<3<* D' =%(D' =%(DE' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*D' =%(D' =%(DE' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*+p+0+   ++0+   +3   !"R(  ~  s *|\`0   (  c ^d 1?"J00,$ 0 2B`S_Ka,1Ka,2e NNx9hvSm^/f&TI{NKa,20" 2$f  (  (  ( ($ ^z p0  p,$D 0d  To ??p0 DO3.3 ]w H2CO3v Ka,1= 4.3010-7 K a,2 = 5.6110-11, {0.0200 moldm-3 H2CO3nm-NH+T vSm^SpH0 zd0n2$f  ( (  (  (  (((  ( ( ( ( (  t%h  c $A  ??w  Pl  ",$D 0H@  !  Zp ?? L85"Ka,2<<Ka,1 Blc(H+)SQN~5uy(2$f   (  (   (  < j   c &A ^??> ^   s d 1?"* > pH =  lg 9. 2710  5 = 4 .03L (2    ( "T     # L}2   N >?"  B   ND>?"P P z     ,$D 0D  T ??  H2CO3 H+ + HCO3 HCO3 H+ + CO32> ,{Nek㉻yubvH+b6RN,{Nek㉻y Vdk c(H+) H" c (HCO3> ) H" 9.2710-5 moldm-3 ~.(2?  ( ( ( ( ( ( ((   (   (   ( ( ( >.(D  3 A?@; D  3 A? 5y0 B  ZD1?"ppB  ZD1?" p pz  +    + ,$D 0d  S A  _?? +  _~N      0 ` 2  N >?"  B  ND>?"P P ~N       2  N >?"  B  ND>?"P P z *   * ,$D 0  c ̳d 1?"*  Tc (CO32> ) = Ka,2c = 5.6110-11 moldm-3+(2    ~N      P P 2  N >?"  B   ND>?"P P H  0޽h ? 3333{___PPT10[+ID' = @B D' = @BA?%,( < +O%,( < +D\' =%(D' =%(D' =4@BBB B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?RCBBCB#ppt_wB*Y3>B ppt_w<*D' =+4 8?\CB#ppt_hBCB#ppt_hB*Y3>B ppt_h<*D\' =%(D' =%(D' =4@BBB B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?RCBBCB#ppt_wB*Y3>B ppt_w<*D' =+4 8?\CB#ppt_hBCB#ppt_hB*Y3>B ppt_h<*D\' =%(D' =%(D' =4@BBB B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?RCBBCB#ppt_wB*Y3>B ppt_w<*D' =+4 8?\CB#ppt_hBCB#ppt_hB*Y3>B ppt_h<*D\' =%(D' =%(D' =4@BBB B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?RCBBCB#ppt_wB*Y3>B ppt_w<*D' =+4 8?\CB#ppt_hBCB#ppt_hB*Y3>B ppt_h<*Di' =%(D' =%(D' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?RCBBCB#ppt_wB*Y3>B ppt_w<*D' =+4 8?\CB#ppt_hBCB#ppt_hB*Y3>B ppt_h<*+8+0+  +7)  D<0!(  x  c $`0     Td ??,$D0 f9hnc]w1_x(x)v㉻y8^peKa(Kb) S{_vQqQmyP[x(x)vKb(Ka)0NAc:NO Ac(aq) + H2O(l) = HAc(aq) + OH(aq) 1(&   (  (  (  (     (      c d 1?"z`,$D0 *8^)ne Kw = 1.0 10 14n 2  (     ( `  c d 1?" f,$D0 j<sS K a K b = Kw , Kwy:N4lvyP[y8^pe 2  (   (  (  ( $f@  l Q]  Q] ,$D0  S A 5??Q] 8 5$D0~N       @ P2  N >?"  B  ND>?"P P xl A  A ,$D0  TH  ?? ,$D0 NAcvqQmx/fHAcHAc(aq) = H+(aq) + Ac(aq) d((2   (    H  S A 7??>0  A 8 7$D0~N     @ p 2  N >?"  B  ND>?"P P l *G `V  !G *`V ,$D0   S A@ 9??*G `V 8 9$D0~N       2  N >?"  B  ND>?"P P ~N     ` 2  N >?"  B  ND>?"P P ~N      / 2  N >?"  B   ND>?"P P H  0޽h ? 3333___PPT10s+D,D' = @B Dj' = @BA?%,( < +O%,( < +D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*!%(D' =-o6Bdissolve*<3<*!D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-o6Bdissolve*<3<* D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-o6Bdissolve*<3<* ++0+  ++0+   ++0+   +(    @P (  x  c $ /`0   ~  c 1d 1?"@ J`1[NqQmxxvi_ vQqQmx:_ RvQqQmx1_0dk~cknxT2& 2$f " #  c 5d 1?"|,$D 0 @Ka0KbNbSk SOsNqQmxxKNv:_^[z~NvsQ|0X! 2 (  (   c <d 1?"P@ ,$D 0 `2 gN*NNCQx vQN ~TN~㉻y8^peR+R:NKa,1TKa,2 qQmxvN ~TN~㉻y8^peR+R:NKb,1TKb,2 [NKN gUOsQ|I 2$f   (  (  (  (  ` b  c Sd 1?"p < ,$D 0 l]wKabKb SBlqQmxx[-NSN*NxbxvKbbKav+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*++0+  ++0+  ++0+  +?  f^P(  r  S v`0   D  c ,xd 1?"  |nmpHv[Km[ pHՋ~(^l,|[) {US0eO0|eu pHx^ |nx0SpeW[>f:ybꁨRU_ d  23 32 2 %f3!~ H  0޽h ? ̙3333y___PPT10Y+D=' = @B +   `(  x  c $`0   ~  T܅ ??@<  TyP[He^ (W1_xvnm-NReQxvqQmx b(W1_xvnm-NReQ勱xvqQmx O_1_xb1_xv㉻y^'Y'Y NMvsa y:N TyP[He^0@C(2""<  B  c Hd 1?"? ,$ 0 JYHAcv4lnm-N HAc(aq) = H+(aq) + Ac-(aq)F&(2 ( ( P B  c d 1?"  ,$ 0 L`ReQNaAc 1uNNaAc = Na++Ac O_HAc㉻ys^aT]yR HAcv㉻y^MNO0V(2 2 (   r  H  0޽h ? 3333  ___PPT10 +%D ' = @B D ' = @BA?%,( < +O%,( < +D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?\CB#ppt_xBCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?dCB0-#ppt_h/2BCB#ppt_yB*Y3>B ppt_y<*D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?\CB#ppt_xBCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?dCB0-#ppt_h/2BCB#ppt_yB*Y3>B ppt_y<*+p+0+  ++0+  +'  p&(  f  3 0e0e @ 5%8c8c     ?1d0u0@Ty2 NP'p<'p@A)BCD|E?`0     T ??pY\ O3.3 (W0.100 moldm-3HAcnm-NReQN[ϑVSONaAc ONaAcvSm^I{N0.100 moldm-3 Bl勶nm-NH+Sm^ pHTHAcv㉻y^0W 2$f (( ( (      "  T( ??@0{ ,$D0 j]㉻yvHAcvSm^:Nx moldm-3 HAc = H+ + Ac> wYSm^/ moldm-3 0.1 0 0.1 s^aSm^/moldm-3 0.1 x x 0.1+x J(' $f   ( ( ( (        l "Zz `    `  ,$D0  S A <??`  8 <$D0    #   P ,$D02  N >?"  B  ND>?"P P     #  0 ,$D02  N >?"  B   ND>?"P P     !#  P ,$D02 " N >?"  B # ND>?"P P  $ c d 1?"p V ,$D0 3c(H+) = x moldm-3= 1.76 10-5 moldm-3, pH = 4.754 2  (   (   (   (   % S A =??Z 6f 8 =$D0> & TL ??g Pm,$D0 NO3.1vk, TyP[He^OHAcN1.34%M:N0.018%, c(H+)N1.34 10-3 moldm-3 Q\0R1.76 10-5 moldm-3(MNO76 P)0[(  (   (  ( (    ( (    H  0޽h ? 3333___PPT10+Q2-D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$%(D' =-o6Bdissolve*<3<*$D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%%(D' =-o6Bdissolve*<3<*%D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*&%(D' =-o6Bdissolve*<3<*&++0+  ++0+$  ++0+&  +  x p  (  x  c $`0     T< ??@  *1_xSvQqQmxb1_xSvQqQmx@b~bvnmwQ gN*N͑'`( 勶nmvpH(WN[VQ NVzʑbYR\ϑxbx Su>fWSS sS[YRvxTxwQ gQR ُynmy\OQnm0:Y( S"&f""5  c , d 1?" `g ,$D0  NHAcTNaAcvmTnm:NO: NaAc == Na++ Ac- HAc(aq) = H+(aq) + Ac-(aq) |~-N'YϑHAc0AcX[(W OH+v[\0S_nm-NReQ\ϑ:_xe H+NAc~TubHAc OH+vSm^OcW,g NS0(  ( ( ( (   ( (    (  #   c !d 1?"` ,$D0 |傀_|~-NReQ\ϑ:_x RH+NOH-~TubH2O OHAc㉻ys^aSy HAcvSm^Q\ H+vSm^NOcW,g NS0n? 2 ( ( ( ( ~  H  0޽h ? 3333LD___PPT10$+Z;D' = @B DS' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(+p+0+  ++0+  +     L (  x  c $6`0   r  T7 ??pP,$D0 LS_ReQ'Yϑv:_xb:_x Onm-NvAc> bHAc=\ Rnm\1YSQR0'(2'".   c &A  ?? "Q 8  $D0D  c =d 1?"P`,$D0 N|~bQnmvN[qQmxx YHAc Ac> Sy:NQ[0S(u_h:yQ[KNX[(Wvs^a qQmx = qQmx + H+f/(     ! (Hl      ,$D0  S A ???  8 ?$D0~N     `p2  N >?"  B  ND>?"P P ~N      p 2  N >?"  B  ND>?"P P ~N     ` ` 2  N >?"  B  ND>?"P P l P M  P  M ,$D0  S A A??P M 8 A$D0~N     P  2  N >?"  B  ND>?"P P H  0޽h ? 3333kc___PPT10C+=ݔD' = @B Dr' = @BA?%,( < +O%,( < +D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-o6Bdissolve*<3<* D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-o6Bdissolve*<3<* +p+0+  ++0+   +4  , $  (  x  c $X^`0   ^  T_ ??',$D 0 DO3.4 40.00 cm3 1.000moldm-3 HAcN20.00cm3 1.000 moldm-3 NaOHmT BlmTmvpH? K 2$f (  (  (  (  P   Tl ???,$D 0 "HAc + NaOH = NaAc + H2O 1uNHAcǏϑ S^s^aTub0.02000molvAc v^iRYO0.02000mol HAc nm;`SOy:N60cm30N/fp] 2$f ("   (     S A!  ??x  8  $D 0  Z z ?? 9 ,$D 0 "]wHAcvpKa:N4.76 VdkF 2  (  @  c &A" I?? `8 I$D 0H  0޽h ? 3333___PPT10+D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(D@' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bwipe(up)*<3<*D' =%(D' =%(D@' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bwipe(up)*<3<*D' =%(D' =%(D3' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bwipe(up)*<3<*D' =%(D' =%(D@' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bwipe(up)*<3<*D' =%(D' =%(D3' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bwipe(up)*<3<*++0+  ++0+  ++0+  +.  V N  (  x  c $`0   L  T ??P`,$D0 50.00cm3Qnm-NReQvxT;`SOy:N50.05 cm3 ReQv1.000 moldm> 3vx1uNzʑ Sm^S:N A(2$f  ( ( (   `   c &A  K??~8 K$D0  T ??  ,$D0 <1uNReQvH+vϑv[Nnm-NAcvϑ _\ S:NReQvH+[hQNAc~TbHAcRP[0N/f c(HAc) = (0.1000 + 0.001)mol dm> 3 = 0.101 mol dm> 3, c(Ac) = (0.1000  0.001)mol dm> 3 = 0.099 mol dm> 36( (   (       ( (         (   (  g  T ??& VDO3.5 ]w(W 50.00 cm3 +T g 0.1000 moldm> 3vHAc T0.1000 moldm> 3 NaAcQm-N ReQ0.050 cm3 1.000 moldm> 3 vx BlvQpH0 k 2$f  ( ( ( (  (     c $A# M??P  <8 M$D0H  0޽h ? 3333 x ___PPT10X +(9D ' = @B D ' = @BA?%,( < +O%,( < +D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*+p+0+  ++0+  +     (  x  c $`0      T ??0 P{~ghf 50 cm3 HAc-NaAcQnm-N 傠ReQ\ϑv:_x(0.05cm3 1.0moldm-3vvx) nmvpH1u4.76M4.74 N9eS0.02FO(W50cm3~4l-NReQ0.05cm3 1.0 moldm-3 HCl nm R1uNH+vSm^~:N0.001moldm-3 pHI{N30sSpH9eSN4*NUSMO0 ( ( (% ( ( ( ( ( b J  T ??0,$D 0 (`QnmvQRNTNV } gsQ4 $f  R  c d 1?",$D 0 \QR;NNN NV } gsQ Qnm-NqQmxvpKa+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*+p+0+  ++0+  +  tl(  x  c $T`0   P  Tl ??0  nc@bpH bQ[ QnmvpH NNSQNQ[-NqQmxvKa ؏SQNQ[-N$Nyir(Sm^vk       (  (   j  c /d 1?" @0 ,$D0 tN,:N S_Q[vSm^k(W0.1T10KNMbwQ gQ\O(u Vdk QnmvpH TpKaKN gN NsQ| pH = pKa 1rC +  (  (   Z H  0޽h ? 3333LD___PPT10$+Z;D' = @B DS' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(+p+0+  ++0+  +0  00-B/(  x  c $C`0   -| T` B #"."8PT`  # lK>> ??+ ` [ 11.66~13.66 Z " @`  # lM>> ?? + U12.66Z" @`4  # lxa>> ?? 8___PPT10N___PPT90( HPO4 2 - PO43 Z"****"**" @`_  # ld>> ??T   Na2HPO4 /NaOHZZ"*"*"  @`  # l\u>> ??+c `  Z 9.25~11.25 Z " @`  # l}>> ??c +  U10.25Z" @`  # l>> ??c  8___PPT10N___PPT90( HCO3 - CO32 zZ"**"**" @`M  # lP>> ??Tc    NaHCO3/Na2CO3jZ"*"*"* @`  # lP>> ??+ `c  Z 8.25~10.25 Z " @`  # ld>> ?? +c  T9.25Z" @`  # l\>> ?? c 8___PPT10N___PPT90(  NH4+ - NH3 j Z"**"*" @`  # l>> ??T c 8___PPT10N___PPT90( NH3H2O /NH4ClZ"*"*""*" @`  # l>> ??+'`  Y 6.21~8.21 Z " @`  # l>> ??'+  T7.21Z" @`.  # l>> ??' 8___PPT10N___PPT90( H2PO4 -HPO42 Z"*"**""** @`m  # lD>> ??T'  NaH2PO4/Na2HPO4Z"*"*"*"* @`  # l>> ??+d`' Y 3.75~5.75 Z " @`  # lt>> ??d+' T4.75Z" @`   # l>> ??d'8___PPT10N___PPT90( HAc -Ac  j Z"*""** @`|   # l>> ??Td' CH3CO2H/CH3CO2NaZ"*"*"*"*" @`   # l>> ??+`d Y 2.75~4.75 Z " @`   # lH>> ??+d T3.75Z" @`   # l)>> ??d8___PPT10N___PPT90( HCO2H -HCO2  Z"*"*""** @`  # ll8>> ??Td x HCO2H/NaOH< Z"*" @`  Z7 ??+` fQV   @`  ZH ??+ pKa4  ( @`  ZPX ?? p qQmxx[  @`  Z` ??T nQnm  @`B   Zo ??T`B ! T1 ??T`B " T1 ??Td`dB # T1 ??T'`'B $ T1 ??T ` B % T1 ??Tc `c B & T1 ??T ` B ' Zo ??T`B ( Zo ??TTB ) T1 ??B * T1 ??B + T1 ??++B , Zo ??``0 A c tdd 1?"  n 8^(uQnmvQV (2  H  0޽h ? 3333y___PPT10Y+D=' = @B +      (  x  c $J`0   D  T ??0 DO3.6 M6R10cm3 pH=5vHAc-NaAcQm Sm^:N1.0 moldm-3vHAcTNaAcnmTY\kGShD 2$f  (! (      c $A  ??`{8  $D 0  c $A% <??p 8 <$D 0D  T ??  ,$D 0 1uN$NSm^v T VdkSSOykT;`SOyn V(HAc)/V(NaAc)=0.562 SV(HAc) + V(NaAc) = 10cm3 VdkV(HAc) = 3.6 cm3V(NaAc) = 6.4 cm3 2W          (   (   (     l     ,$D 0h  c $A' 8??  8  c d 1?" T 2fH  0޽h ? 3333{ s ___PPT10S +ВyD ' = @B D ' = @BA?%,( < +O%,( < +D' =%(D' =%(DC' =4@BBB B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-6B#strips(downLeft)*<3<* D' =%(D' =%(DC' =4@BBB B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B#strips(downLeft)*<3<*D' =%(D' =%(DC' =4@BBB B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B#strips(downLeft)*<3<*D' =%(D' =%(DP' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B#strips(downLeft)*<3<*+8+0+  +  L(  r  S ,`0     c d 1?"0  DO3.7 1.k TSm^Na2S, NaAc, NaCN, Na2CO3nmpHv'Y\0(]w gsQvKa, Kb) 2.['`k0.10mol.dm-3 NRnmvpH(9hncSf[wƋ)0 HAc, HAc + NaAc, H3PO4 , NaAc, Na2CO 3 , NaOH` 2$f $f ( ( (  (  ( ($ ( (  ( ( :    H  0޽h ? ̙3333y___PPT10Y+D=' = @B +   (  x  c $H`0   :  T| ??0  MyP[TMMOSTir 1u-N_yP[b-N_SP[Tr^*N-N'`RP[b[yyP[y:NMMOSO ǏMMO.~T bv YBgyP[SZPMyP[~yP[ Y[Cu(NH3)4]2+0[Ag(NH3)2]+0\ 2 &f.   ( ( ( ( ( ( B  c d 1?" ,$D0 2+T gMyP[vSTiry:NMMOSTir(MTir ~Tir)0Y [Cu(NH3)4]SO4 MyP[N{USyP[wQ g_ Nv Tv'`(0Y CuSO4 + 2NaOH !Cu(OH )2 + Na2SO4 CuSO4+NH3(Ǐϑ)![Cu(NH3)4]SO4m݄r [Cu(NH3)4]SO4 + NaOH!elm    ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( (  + H  0޽h ? 3333___PPT10+RQDO' = @B D ' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(+8+0+=  +h      (  x  c $`0     T ??p0 x*S㉻yvMTir_NyMv Mv1u$NR~b  2&f   c d 1?"`,$D0 l MyP[ 1u-N_SP[(b-N_yP[)NMMOSONMMO.~Tv0&^5uwvSP[V0MyP[ NQwQ g{USyP[S gv'`(L 2 $f1  > %  c @ d 1?",$D0 6 &^ gNMyP[_S5uwvyP[ RNOYuvQS gv'`(@  $f l     ,$D0  c d 1?" ,$D0 Mv(W4l-NS[hQ㉻yY Cu(NH3)4]SO4 ! [Cu(NH3)4]2++SO42- MyP[{|+B#style.visibility<*%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* %(+p+0+=  ++0+=  +s    0j (  x  c $4`0     S A$ ?? SF8 $D0  Z,7 ?? @  ~S__euSm^ϑ~e S{S:N$ 2   D8 `g  `g j  c &A O??`g  O~N        @2  N >?"  B  ND>?"P P ~N     `  P2  N >?"  B  ND>?"P P ~N     @ pP2  N >?"  B  ND>?"P P 8    T(B ?? [Cu(NH3)4]2+MyP[;`v㉻ys^aS{USh:y:N [Cu(NH3)4]2+ Cu2+ + 4NH3 vQ;`v㉻y8^peK㉻ybKi (Instability Constant):N$t(  ( ( (% ( ( ( ( ( (  (  ( ` "B  # lD1?"PP QB B # lD1?"P H  0޽h ? 33335-___PPT10 +AكD' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*+  @ <(  x  c $[`0   @  T\\ ?? 1 [N TN{|WvMyP[ K㉻y'Y MyP[f㉻ysS N3z[0Vdk MyP[v㉻ys^a8^peSy\O N3z[8^pe (uK i (K N3z)h:y0C 2 ""* "&f""*""**" H )l P   g  ,$D0  Thj ??P   T>f6q  2 h  c $A, H??  H  S A) ??0v8 $D0  c &A& ?? HP 8 $D0B  s od 1?"P0 ,$D0 F`MyP[v3z['`SN(u3z[8^peKf (Formation Constant bKub)h:y [INz1 2 "&f"*""*"HH  0޽h ? 3333___PPT10+^D~' = @B D9' = @BA?%,( < +O%,( < +D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* %(+  VNP(  x  c $`0   P  c ؂d 1?"p`V &`(WNHN`Q NSNOOMyP[㉻y2 2$f    c 4d 1?"`B,$D0 hReQSNNMyP[-Nv-N_yP[bMSOubf㉻yvSTirMNOnm-N-N_yP[bMSOvSm^ OMyP[ Ne㉻y05 25 4l `0  `0 ,$D0t Y0   `0 ,$D0r  Tl ??Y0  N MNO-N_yP[vSm^ [Cu(NH3)4]2+ Cu2+ + 4NH3 + Na2S! Na+ + S2- ! CuS! @  " " ( ( (  ( ( (T ( ( (  4B    `D1?"p p N  0@   z j @B  # lD1?" 0 B B # lD1?"@ 0@ Bl  p  p,$D0t  p  p,$D0  T ?? p Nj MNOMSOvSm^ [Cu(NH3)4]2+ Cu2++4NH3 + HCl! Cl- + H+ = NH4+ z (p(  =  " ( ( ( ( ( ( = '  ( ( ( (( FB    `D1?" N  0@   0 0 P ` B  # lD1?" 0 B B # lD1?"@ 0@ H  0޽h ? 3333C;___PPT10+ID' = @B D' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* %(D4' =%(D' =%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(+8+0+ G  +<   XP`(  x  c $`0   b  T8 ??p1 pSn5u(v㉻ys^a/fUSvSO|vyP[s^a0n5u((W4lnm-N X[(WVSOTnm-NyP[KNvs^a sSYvyP[s^a089 21"&f"8  T ??70 ,$D 0 Pnvv[IN `N` N\100g H2O-Nn㉦^\N0.01gvir(y\Onir0L) 2&f" ( N H  0޽h ? 3333___PPT10d+6D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*+8+0+q  +1  D < p  (  x  c $`0     T ??pw ,$0 Tn^y (WN[)n^ N nN~vfsvI{e O^zNVSOTnm-NyP[KNvR`s^a y:NYvyP[s^abns^a dkevnmy:NqTnm0YCaCO3(W4l-Nvn㉦^}\ FON gN[peϑvCa2+0CO32-X[(WNnm-N0 Te nm-NvCa2+NCO32-SO~T NegQ0 CaCO3(s) = Ca2+(aq) + CO32-(aq)(( "(     ( ( (( ( (( ( ( (( `E  !T  c d 1?"0 0 ,$0 ^bS_)n^N[e vQyP[Sm^vXNy:NN8^pe ُ*Ns^a8^peKs(eyKsp)y:Nn^y8^pe {yn^y02   (  (      @l  _    _ ,$D0>@ o _   o _ h  c $A+ Q??o _  Q~N     @ p@ 2  N >?"  B  ND>?"P P >    d 1?"   bs^a8^peh_:N$ $f  H  0޽h ? 3333  ___PPT10m +E D ' = @B D ' = @BA?%,( < +O%,( < +D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-o6Bdissolve*<3<* D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*+p+0+ ++0+ +    > (  x  c $`0     T  ??`> |~n5u(vn^yTn㉦^h:yvQnRv'Y\0 傶n㉦^Ns moldm-3h:y ABWnir( YAgCl, CaCO3, BaSO4I{ g CaCO3(s) = Ca2+(aq) + CO32-(aq) s^aSm^/moldm-3 s s Ks (CaCO3) = s2f    ( ( ( ( ( (( (       ( (  ( t  ?,  T(6 ??h0: ,$D0 t0A2BWbA2BWnir( YAg2CrO4 Mg(OH)2I{ g Ag2CrO4(s) = 2Ag+(aq) + CrO42-(aq) s^aSm^/moldm-3 2s s Ks (Ag2CrO4) = (2s)2s = 4s3"w  ( ( ( ( ( ( ( ( (( (    ( ( (   (   (`#A  c Ud 1?"0  ,$D0 *`SN(uKsv'Y\$Ren㉦^v'Y\TX 2$f   ( , z  c l[d 1?"* ,$D0 * T{|Wvir(SN$Re N T{|We N$Re0 2$fH  0޽h ? 3333___PPT10+>+D' = @B D' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(++0+G  ++0+G  ++0+G  +C  @(  x  c $j`0   $  Tl ??`> [ T{|Wvn5u( S(un^yKsv'Y\egkn㉦^sv'Y\0FO N T{|Wvn5u(R N[vc(un^yKsv'Y\egkn㉦^sv'Y\0YG 2""* """"* """R    c xd 1?"P' ,$D0  n^y CaCO3 AgCl Ag2CrO4 Ks 8.710-9 1.5610-10 910-12 s 9.410-5 1.2510-5 1.3110-4 sQ|_ L 2  (  ( (  ( (  (  (   ( ( ( . l  c $AA W??0 0 a 8 W$D0  c $AA X?? p P 8 X$D0  c $A Y??  P 8 Y$D0H  0޽h ? 3333; 3 ___PPT10 +f.lD ' = @B Dz ' = @BA?%,( < +O%,( < +D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*+8+0+G  +     ` (  x  c $(`0     Z\ ??0L z1. n^yĉR AnBm(s) = nAm+(aq) + mBn-(aq) Qc:NNar` N gsQyP[Sm^vXNysSSm^FU> 2& f ( (   (   (  (  ~  s *A. L??v 8 L$D 0l @   @ ,$D 0  T ??@ ,$D0 Qc Ks glmgQv󁾏qT Qc = Ks n㉾s^a qTnm (3.20) QcKs elmgQ blmnO 2 (  (  (  (  (  ( F     s d 1?" @` f   c d 1?"* ,$D 0 p$n^yĉRS(uN$R+RlmvSubn 2 H  0޽h ? 3333\ T ___PPT104 +*<D ' = @B D ' = @BA?%,( < +O%,( < +D' =%(D' =%(D7' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-s6Bwipe(left)*<3<*D' =%(D' =%(D7' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-s6Bwipe(left)*<3<* D' =%(D' =%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-s6Bwipe(left)*<3<* +8+0+ G  +     (  x  c $ )T   L  TD ??<,$0 hDO3.7^4l-NCr3+vSm^:N 0.010 moldm-3, ReQVSONaOHOKNubCr(OH)3 lm, ReQVSONaOHTnmSOy NS { 1) _Yublme nmOH-yP[vgNOSm^; 2) 傁OCr3+vSm^\N4.0mgdm-3(7.710-5 moldm-3)N0Rc>ehQ dkenmvpHg\^:NY\ 2$f ( ( (- ( (  ( ( (        c d 1?"8 T9 ,$0 1) Cr(OH)3(s) = Cr3+(aq) + 3OH(aq) ublme Qc > Ks c(OH) = x c(Cr3+) c(OH)3 = 0.010x3 > 6.310-31 _ x > 4.010-10 moldm-3t( $f ( (    ( (    (         (     (  (  ( (     ( ( L! 3  c d 1?"_ PY,$0 2) 7.710-5x3 6.310-31, ㉗_ x 2.010-9 moldm-3 pOH =  lg c(OH) < 8.7 sSpH g" 14  8.7 = 5.3\`  ( (  ( (    ( (       $$ ( (, , 0 0V H  0޽h ? 3333___PPT10+3@D' = @B D' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(++0+O  ++0+O  ++0+O  +   |t (  x  c $3`0   |  T5 ??p` Blmn㉄vagN MNOn^y8^pe-NvsQyP[vSm^ O_QcKs "  "  (  ("   TlG ??- ,$0  )R(uxxS^ CaCO3(s) ! Ca2+ + CO32-+ H+ H2O + CO2! c(CO32-) NM QcKs CaCO3n0 SY Rё^\kxSirFeS0ZnS0MnS0NiSI{nNzx ZnS + 2H+ Zn2+ + H2S! R(g(   $f (   ( (( ( (  ( (   ((  (  (( (0 (  ( ( 2  H  0޽h ? 3333___PPT10+PQFDO' = @B D ' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(+8+0+O  +  \T(  x  c $h`0     To ??p ,$D0 *| )R(u~TMMO S^ AgCl(s) + NH3 ! [Ag(NH3)2]+ + Cl c(Ag+) NM,O_QcKs0 (3(  $f ( ( ( (     (  (  ( Z J  T~ ??,$D0  )R(u'lS؏SS^ S gNNё^\kxSirYAg2S0CuS0PbSI{ vQKs*Y\ NnN^'lS'`x FOSReQ'lS'`x g'Y0WMNONSyP[vSm^ OKNn0 3PbS + 8HNO3(z) = 3Pb(NO3)2 +3S!+2NO!+4H2O (o(  $f (  (   (  ( (  (   H  0޽h ? 3333LD___PPT10$+ŘD' = @B DS' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(+p+0+O  ++0+O  +      (   ~   s *ę`0   p   T ??@ p(Wn5u(qTnm-N ReQ+T gNnir~b-Nv TyP[v:_5u( On5u(vn㉦^MNOvsay:N TyP[He^0F9 2"&f"#8   T$ ?? ,$D0 $0 TyP[He^O_Qc > Ks OY(WAgClqTm-NReQNaCle 1uNClyP[v'YϑX[(W OAgClvn㉦^ NM0 AgCl(s) == Ag+ + Cl NaCl == Na+ + Cl c(Cl) NGS O_Qc > Ks(AgCl) dkec(Ag+) NMsSAgClvn㉦^ NM0<(](   (  (  $ (   (         (    (     (  :  6   c d 1?" 0%,$D0 @D`:AgCl(s)(W0.01mol.dm-3 NRnm-Nvn㉦^k(W4l-N'Yv/f ( ) (1)KCN (2)AgNO3 (3)NH3 (4)NaCl 2$f  (j ( ( ( Nd%1   c d 1?" ` ,$D0 ;3 2H   0޽h ? 3333___PPT10+RQDO' = @B D ' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(+8+0+y +j  H @ $ (  $~ $ s *`0   h $ T ??pP`v DO3.8{BaSO4(W0.100 moldm-3 Na2SO4nm-Nvn㉦^ v^NvQ(W4l-Nvn㉦^k0Ks (BaSO4) =1.0810-10O 2f (  ( ( (  ( (  (F $ T ?? ,$0 `Rs moldm-3:NBaSO4(W0.1 moldm-3 Na2SO4nm-Nvn㉦^ BaSO4(s) = Ba2+ + SO42- s^aSm^/moldm-3 s s + 0.1 Ks = s (s + 0.1) 0.1s = 1.0810-10 ㉗_s =1.0810-9r/ F( 5 f      (   (   (   (   (   (   (   (  (   (        (            (     (  x L z ^ p $ ^ p,$D0 $ c d 1?"^ p BaSO4(W~4l-Nvn㉦^:Nsomoldm-3 so = =1.0410-5 n㉦^MNON~104 (NN) P0F  (  (   ( ( (  (  H %h $ c $A  ??% P   H $ 0޽h ? 3333___PPT10+qDN' = @B D ' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =%(D' =%(DG' =4@BBB B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-6B'blinds(horizontal)*<3<* +8+0+y +   ((  (~ ( s *)`0    ( T0 ??@,$D 0  ]N NuNAl2O3 vǏ z Al3+ + OH! Al(OH)3 ! Al2O3 ReQS_ǏϑvlmBRCa(OH)2 SNOnm-NAl3+lm[hQ0 ` ǏϑlmBR9e:NNaOHLTr 2R &f.f&f.f&f (   ( ( ( (  ( $f  (~ 6 ( c Ad 1?"0 @H,$D 0 @ Ŕ(u\O3gPge SY (WkxxbkxxvN(-NۏL5u@bvQN5uSf[Yte 8^SN(u^NvŔ5ugSNf5v”5ug(u\O3gPge01\/f1uNX[(W'Yϑvkxx9hyP[ V TyP[He^O_Ŕ5ughbvkxxŔgn0> 2Z 2 &fZ aH ( 0޽h ? 3333___PPT10+͑D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-6B%strips(downRight)*<3<* D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-6B%strips(downRight)*<3<* +p+0+   ++0+   +   ,f(  ,~ , s *hR`0     , TY ??2 NylmTSNyfnvlmlSvǏ zy:NlmvlS Y PbCl2 + 2I = PbI2!+ 2Cl }v Ğ Ks(PbCl2) = 1.610-5 Ks(PbI2) = 1.3910-8Zt "&f"      a!a!  $ . , ZXl ??^Q,$D0 .lmlS^(u p-NvWv;NbR:NCaSO4(Ks =7.1010-5 ),1uN CaSO4 NnNx NdS0(uNa2CO3nmYt SlS:NfnFO(0Wu~g0fnNxvir(  CaCO3 (K s =4.9610-9 ) N SN[f0W(uxI{1_xnd0(W[E^(u-N(uvxegNfx0* &f (  ( ( ( ( ( (  (  ( (! Z  H , 0޽h ? 3333___PPT10+!A`DO' = @B D ' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$%(+8+0+$  +G   $ 0(  0~ 0 s *d`0   F 0 T ??`E ^4lYt +THg2+^4lSN(ukxSirۏLYt FO(ufnkxSirYNa2SI{ۏLYte YtTv4l-NX[(W'YϑvkxyP[ bevalg0)R(ulmlSvel Y(uFeSYt+THg2+^4l RSN㉳Qُ*N0z`8n&f ( (2 ( \)  0 c Td 1?"@t ,$D0 FeS(s) + Hg2+(aq) = HgS(s) + Fe2+(aq), K" =7.9 1033 VǏϑvFeS NnN4l SNǏndS0K8 n ( ( (  (   ( B H 0 0޽h ? 3333___PPT10+RQDO' = @B D ' = @BA?%,( < +O%,( < +DA' =%(D' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*(%(+8+0+(  +   04(  4~ 4 s *`0    4 c Dd 1?" FNybQyir(Rce(WSNyir(-N@bb_bv|~y:NRce|~ {yRce|0^$ 2#'f#'f# $| 4 c Ԯd 1?"@&,$D 0  Rce|-NRcevir(y:NRcev00 2 $f z 4 c Dd 1?"`F,$D 0 Rcev@bYvN(y:NRceN(00 2 $f  4 c d 1?"0V ,$D 0 R`(um|T4l6Rbvm||/fNyRce|~0cQRce|~-NvRcevTRceN(0.* 2f' )| 4 c d 1?"` F ,$D 0 ,(Wm||-N Rcev/fm|| RceN(/f4l0 2$fH 4 0޽h ? 3333RJ___PPT10*+*D. ' = @B D ' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* 0%(D' =-6B%strips(downRight)*<3<* 0D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* 0%(D' =-6B%strips(downRight)*<3<* 0D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* 0%(D' =-6B%strips(downRight)*<3<* 0D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*0%(D' =-6B%strips(downRight)*<3<*0++0+ 0  ++0+ 0  ++0+ 0  ++0+0  +'  @ 8`(  8x 8 c $`0   h 8 T ??p  cRcev|P[v'Y\R{|, v32g  f !0 !0  8 c d 1?"0,$D0 X RP[RceSO|Rcev|P[vv_\N10-9m ^\Nwnm0OY/lS0a|I{4lnm0Z-a   ( a  <!0+!0,-!0+!0,-, 8 c d 1?"0,$D0 d SORceSO|Rcev|P[vv_(W10-9m~ 10-7mKN ^\NSO0OYˆ}v(08hxI{4lnm0t3a   ( ( a  L!0!0!0!023!0!0!0!0232 8 c ,d 1?"0| ,$D0 <N |RceSO|Rcev|P[vv_'YN10-7m fZl0OY[rvY FFm lFmI{0J(a   ( `!0!0!0!0!0!0 8 T ?? p ,$D0  cSON4lvNTRR{|, v32g  f !0 !0 * 8 c Td 1?" 0| ,$D0 46amn Rcev|P[N4lvNTR1_ YAgISOI{0Ta   a  &!0!0  8 c l d 1?" 0\,$D0 :Nmn Rcev|P[N4lvNTR:_ Yˆ}v(0m|I{0 Ba  .  !0!0!0!0H 8 0޽h ? ̙3333jb___PPT10B+!fD' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-o6Bdissolve*<3<* D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-o6Bdissolve*<3<* D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-o6Bdissolve*<3<* +P+0+  ++0+  ++0+  ++0+   ++0+   ++0+   +<  ""P**<&"(  <~ < s *&`0   V < T) ??  @ ,$D0 NxSSO:NO AgNO3 + KI(Ǐϑ) ! 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